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Published on: August 23, 2012
Supramolecular n/p-heterojunction photosystems with oriented multicolored antiparallel redox gradients (OMARG-SHJs)
Rajesh Bhosale1, Jirí Mísek, Naomi Sakai
1Department of Organic Chemistry, University of Geneva, Geneva, Switzerland.
Abstract:
Directional electron and hole transport is essential in photosynthesis. Applied to molecular optoelectronics such as organic solar cells, these lessons from nature call for oriented supramolecular n/p-heterojunctions (SHJs) that contain various chromophores and antiparallel redox gradients (OMARGs). In this tutorial review, we summarize recent progress made toward the construction of OMARG-SHJs. This conceptually innovative twist added to a timely topic should appeal to the synthetic organic, supramolecular, biological, physical, analytical and materials chemist as well as to the expert in energy and environmental sciences.
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