Related Experiment Video
Updated: Jun 17, 2026

07:17
Non-equilibrium Microwave Plasma for Efficient High Temperature Chemistry
Published on: August 1, 2017
Drum dispersion equation for Littrow-type prism spectrometers.
M Sidran1, H J Stalzer, M H Hauptman
1Research Department,Grumman Aircraft Engineering Corporation, Bethpage, NewYork 11714, USA.
Applied Optics
|January 6, 2010
Summary
A new method calibrates Littrow-type prism spectrometers using only three readings. This simple procedure accurately determines wavelengths across the ultraviolet to infrared spectrum, enhancing spectral analysis.
Area of Science:
- Spectroscopy
- Optical Instrumentation
Background:
- Littrow-type prism spectrometers are crucial for spectral analysis.
- Accurate wavelength calibration is essential for precise spectroscopic measurements.
Purpose of the Study:
- To develop a simple analytic procedure for calibrating the wavelength drum of a Littrow-type prism spectrometer.
- To achieve high accuracy in wavelength calibration across a broad spectral range (UV to IR).
Main Methods:
- Utilized an approximate expression derived from geometrical optics: D = A - B(a(2) - n(2))((1/2)).
- Required only three measured drum readings for calibration.
- Applied the procedure to a sodium chloride prism for wavelengths from 0.3 µm to 2.25 µm.
Main Results:
- The procedure accurately calibrates the wavelength drum over a broad spectral range (UV to IR).
- Achieved calibration accuracy comparable to instrumental accuracy.
- Computed drum positions agreed with measured positions within experimental error.
- Successfully computed unknown wavelengths with high accuracy.
Conclusions:
- The developed analytic procedure offers a simple and accurate method for wavelength calibration of Littrow-type prism spectrometers.
- The method is applicable to various prism materials with known refractive index data.
- This calibration technique enhances the precision of spectral analysis in the UV to IR regions.
More Related Videos
Related Concept Videos
IR Spectrometers
There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration
A covalently bonded heteronuclear diatomic molecule can be modeled as two vibrating masses connected by a spring. The vibrational frequency of the bond can be expressed using an equation derived from Hooke's law, which describes how the force applied to stretch or compress a spring is proportional to the displacement of the spring. In this case, the atoms behave like masses, and the bond acts like a spring.
According to Hooke's law, the vibrational frequency is directly proportional to the...
According to Hooke's law, the vibrational frequency is directly proportional to the...
X-ray Crystallography
The size of the unit cell and the arrangement of atoms in a crystal may be determined from measurements of the diffraction of X-rays by the crystal, termed X-ray crystallography.
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
The de Broglie Wavelength
In the macroscopic world, objects that are large enough to be seen by the naked eye follow the rules of classical physics. A billiard ball moving on a table will behave like a particle; it will continue traveling in a straight line unless it collides with another ball, or it is acted on by some other force, such as friction. The ball has a well-defined position and velocity or well-defined momentum, p = mv, which is defined by mass m and velocity v at any given moment. This is the typical...
Determination of Crystal Structures
In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...

