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Fabricating Nanogaps by Nanoskiving
Published on: May 13, 2013
Systematic cross-linking changes within a self-assembled monolayer in a nanogap junction: a tool for investigating
1The Department of Chemical Engineering and Russell Berrie Nanotechnology Institute, Technion-Israel Institute of Technology, Haifa 32000, Israel.
Journal of the American Chemical Society
|January 22, 2010
Abstract:
Here, we show that a controllable cross-linking within a self-assembled monolayer can be used as a tool for investigating the (lateral) intermolecular coupling between adjacent organic molecules. We draw this conclusion based on macroscopic electrical experiments with self-assembled hexyltrichlorosilane (HTS) having different degrees of Si-O-Si intermolecular bonds in a planar nanogap junction.
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