Related Experiment Video
Updated: Jun 16, 2026

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing
Published on: March 22, 2019
Infrared-Emission Studies of Electronic-to-Vibrational Energy Transfer. IV: Hg + HF
Abstract:
Electronic-to-vibrational transfer has been observed for the process Hg* (6(3)P(1,0)) + HF(upsilon=0) ? Hg(6(1)S(0)) + HFdagger(upsilon=1-6). (The asterisk symbolizes electronic excitation, the dagger indicates vibrational excitation.) The observations were made by recording ir emission from HFdagger(v=1-6). A set of relative rate constants k(upsilon) were obtained from the observed stationary-state concentrations N(upsilon). The k(upsilon) decrease rapidly with increasing upsilon, up to upsilon = 6. From a comparison of the total HF emission intensity with total CO emission (due to Hg* + CO) a rough absolute cross section Q(E,V) ~ 5 A(2) was obtained for electronic-to-vibrational transfer in Hg* + HF collisions.
Related Concept Videos
Infrared (IR) Spectroscopy: Overview
Different compounds display unique properties due to their...
IR Spectroscopy: Molecular Vibration Overview
Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...
UV–Vis Spectroscopy: Molecular Electronic Transitions
IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration
According to Hooke's law, the vibrational frequency is directly proportional to the...
Emission Spectra
IR Frequency Region: X–H Stretching

