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Metal chalcogenide nanoclusters with 'tailored' surfaces via 'designer' silylated chalcogen reagents

Daniel G MacDonald1, John F Corrigan

  • 1Department of Chemistry, The University of Western Ontario, London, Ontario, Canada N6A 5B7.

Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences
|February 17, 2010
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.