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Updated: Jun 16, 2026

Discovery and Synthesis Optimization of Isoreticular Al(III) Phosphonate-Based Metal-Organic Framework Compounds Using High-Throughput Methods
Published on: October 6, 2023
Heterodinuclear Fe(III)Zn(II)-bioinspired complex supported on 3-aminopropyl silica. Efficient hydrolysis of
Clovis Piovezan1, Rafael Jovito, Adailton J Bortoluzzi
1Laboratório de Bioinorgânica e Cristalografia, Departamento de Química, Universidade Federal de Santa Catarina, Campus Trindade, BR-88040-900 Florianópolis SC, Brazil.
Abstract:
Presented herein is the synthesis and characterization of a new Fe(III)Zn(II) complex containing a Fe(III)-bound phenolate with a carbonyl functional group, which was anchored to 3-aminopropyl-functionalized silica as the solid support. The catalytic efficiency of the immobilized catalyst in the hydrolysis of 2,4-bis(dinitrophenyl)phosphate is comparable to the homogeneous reaction, and the supported catalyst can be reused for subsequent diester hydrolysis reactions.
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