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Updated: Jun 16, 2026

Non-equilibrium Microwave Plasma for Efficient High Temperature Chemistry
Published on: August 1, 2017
Nonlinear absorption of SF(6) at high infrared intensities and high pressures
Abstract:
An experimental study of the saturable absorption of SF(6) at high pressure (up to 500 Torr) with high laser irradiance is presented. Experiments carried out at the P(28) line of the CO(2) laser show a decrease of transmittance with increasing laser irradiance before bleaching sets in. This is explained by a theoretical model using a single rate equation. The decrease of transmittance is shown to be due to vibrational excitation, whereas bleaching is caused by rotational hole burning. Previous results on saturation behavior of SF(6) at the P(16) line of CO(2) reported by Armstrong and Gaddy are given a new interpretation using the present model.
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