Polarization of the reflectivity of paints and other rough surfaces in the infrared

In this study the IR reflectivity of painted and rough surfaces was investigated, and an attempt was made to represent the surfaces by a complex refractive index. A CO(2) laser was used as a collimated source in the thermal IR region, and the polarization properties of reflected radiation were measured. The samples chosen were flat surfaces of sandblasted aluminum, concrete, painted metal, and asphalt. Values of the bidirectional reflectance function were obtained in the two orthogonal states of polarization, based on sulfur as the Lambertian standard. Many samples, such as painted metals, showed specular behavior and could be characterized by Fresnel equations. For some of these surfaces optical constants were calculated from the reflectivity measurements. Good agreement was obtained between the calculated and measured values of the percent of polarization for these surfaces.