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Updated: Jun 15, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Reversible aggregation of X-shaped bolaamphiphiles with partially fluorinated lateral chains at the air/water
Patrycja Nitoń1, Andrzej Zywociński, Robert Hołyst
1Institute of Physical Chemistry PAS, Kasprzaka 44/52, 01-224 Warsaw, Poland.
Abstract:
Langmuir films of four X-shaped bolaamphiphiles were studied using surface pressure and Kelvin potential measurements, Brewster angle microscopy and X-ray reflectivity. The partially fluorinated bolaamphiphiles exhibit an unusual reversibility and reproducibility of Langmuir isotherms, and create very stable and well defined single- or triple layers which can be transferred to solid substrates.
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