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Updated: Jun 14, 2026

Preparation of Silver-Palladium Alloyed Nanoparticles for Plasmonic Catalysis under Visible-Light Illumination
Published on: August 18, 2020
Layer-by-layer deposition of silver/gold nanoparticles for catalytic reduction of nitroaromatics
Subhra Jana1, Surojit Pande, Arun Kumar Sinha
1Department of Chemistry, Indian Institute of Technology, Kharagpur 721302, India.
Abstract:
A general method has been fabricated to achieve normal as well as inverted core-shell architectures of silver/gold through a layer-by-layer deposition technique on a commercial anion exchange resin. Electrostatic field force of the charged resin beads supports immobilization of anionic metal precursors [MX(n)]-, in turn deposition of silver/gold nanoparticles onto the solid resin matrix and reduction of 2-nitrobenzoic acid to obtain the corresponding amines through effective catalysis. The shell thickness has been tailored made by exploiting a new method of cyclic and repetitive deposition of the desired metal precursors. Thermodynamic parameters for the reduction reaction have been presented. Kinetic study reveals a comparative account of rates between the mono- and bi-metallic nanoparticles where silver stands to be a better catalyst for the reduction of nitroaromatics.
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