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Colour tuneability in sol-gel nano-glass-ceramics comprising Yb(3+)-Er(3+)-Tm3+ Co-doped NaYF4 nanocrystals
J Méndez-Ramos1, A C Yanes, A Santana-Alonso
1Departamento Física Fundamental y Experimental, Electrónica y Sistemas, Universidad de La Laguna, 38206 La Laguna, Tenerife, Spain.
Abstract:
White light can be obtained by up-conversion processes in a cheap and efficient way, being of great interest for lighting, displays, and photonic integrated devices. Here we report a generation of white light under 980 nm laser infrared excitation in Y(b3+)-Er(3+)-Tm3+ triply doped sol-gel derived nano-glass-ceramics containing NaYF4 nanocrystals where co-dopants ions are partitioned. Efficient simultaneous blue, green, and red up-conversion emissions give rise to a balanced white overall emission and corresponding up-conversion mechanisms have been analyzed. Changes in pump power intensity or heat treatment temperature widely vary the ratio of emission bands, resulting in a colour tuneability which has been analyzed and quantified in terms of CIE standard chromaticity diagram.
