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Cycle formation from acetylene addition on C4H3 radicals

Xavier Lories1, Jacques Vandooren, Daniel Peeters

  • 1Laboratoire de Chimie Quantique, Université catholique de Louvain, Département de Chimie, Bâtiment Lavoisier, Place Louis Pasteur, 1, B-1348 Louvain-la-Neuve, Belgium.

Physical Chemistry Chemical Physics : PCCP
|April 2, 2010
PubMed
Summary

This study investigates acetylene addition reactions on hydrocarbon radicals. New cyclization pathways and dehydro-fulvene radical formation were identified as energetically competitive routes.

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