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Ionic Radii03:10

Ionic Radii

33.6K
Ionic radius is the measure used to describe the size of an ion. A cation always has fewer electrons and the same number of protons as the parent atom; it is smaller than the atom from which it is derived. For example, the covalent radius of an aluminum atom (1s22s22p63s23p1) is 118 pm, whereas the ionic radius of an Al3+ (1s22s22p6) is 68 pm. As electrons are removed from the outer valence shell, the remaining core electrons occupying smaller shells experience a greater effective nuclear...
33.6K
Ionic Bonds00:42

Ionic Bonds

131.0K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
131.0K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

20.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
20.1K
Solubility of Ionic Compounds02:55

Solubility of Ionic Compounds

68.2K
Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
68.2K
Ionic Crystal Structures02:42

Ionic Crystal Structures

17.1K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
17.1K
Ionic Compounds: Formulas and Nomenclature03:34

Ionic Compounds: Formulas and Nomenclature

87.5K
An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
87.5K

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Related Experiment Video

Updated: Feb 5, 2026

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid
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Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid

Published on: January 25, 2020

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Nanoporous carbon supercapacitors in an ionic liquid: a computer simulation study.

Youngseon Shim1, Hyung J Kim

  • 1Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, USA.

ACS Nano
|April 3, 2010
PubMed
Summary
This summary is machine-generated.

Supercapacitors using carbon nanotube (CNT) micropores show ion distribution changes with pore size. Smaller pores exhibit unique multilayer ion arrangements, impacting capacitance performance.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Computational Chemistry

Background:

  • Supercapacitors are advanced energy storage devices.
  • Carbon nanotubes (CNTs) and ionic liquids are key components in supercapacitor technology.
  • Understanding ion behavior in nanopores is crucial for optimizing supercapacitor performance.

Purpose of the Study:

  • To investigate the behavior of room-temperature ionic liquid (RTIL) ions within CNT micropores.
  • To explore the relationship between CNT pore size and ion distribution.
  • To analyze the impact of ion distribution on supercapacitor specific capacitance.

Main Methods:

  • Molecular dynamics (MD) simulations were employed.
  • Simulations focused on 1-ethyl-3-methylimidazolium tetrafluoroborate (EMI+BF4(-)) within various CNT diameters.
  • Analysis included ion distribution, solvation structures, and specific capacitance.

Main Results:

  • RTIL ion distribution varied significantly with CNT pore size.
  • Small CNTs showed exclusive counterion solvation with alternating charge density layers.
  • Larger CNTs exhibited multilayer solvation of both counterions and coions.
  • Specific capacitance increased with decreasing CNT diameter down to (7,7) but decreased rapidly for (5,5) pores.

Conclusions:

  • CNT pore size dictates RTIL ion distribution and solvation structure.
  • A multilayer charge model explains observed ion behavior and capacitance.
  • Findings align with experimental results for carbon-based supercapacitors.