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High Throughput Single-cell and Multiple-cell Micro-encapsulation
Published on: June 15, 2012
Non-, micro-, and mesoporous metal-organic framework isomers: reversible transformation, fluorescence sensing, and
Hai-Long Jiang1, Yoshiro Tatsu, Zhang-Hui Lu
1National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan.
Abstract:
For the first time, three novel metal-organic framework (MOF) isomers with hierarchical channel sizes of nonpore or micropore or mesopore were successfully prepared by simply controlling the amounts of solvent or/and reaction temperatures/time. Strikingly, we have demonstrated the reversible transformation between the microporous and mesoporous MOFs triggered by solvent or/and temperature perturbation. The desolvated microporous MOF has been evaluated to be a promising luminescent probe for detecting small molecules, and the mesoporous MOF could be the stationary phase in high-performance liquid chromatography (HPLC) for size-exclusion separation of large dye molecules.
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