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Ultrahigh Density Array of Vertically Aligned Small-molecular Organic Nanowires on Arbitrary Substrates
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Alexey Bezryadin1, Paul M Goldbart

  • 1Frederick Seitz Materials Research Laboratory Department of Physics University of Illinois at Urbana-Champaign Urbana, Illinois 61801, USA. bezryadi@illinois.edu

Advanced Materials (Deerfield Beach, Fla.)
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Single molecules like DNA or carbon nanotubes template ultra-thin superconducting nanowires. These wires exhibit quantum effects like macroscopic quantum tunneling due to thermal fluctuations affecting their superconductivity.

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Area of Science:

  • Nanotechnology
  • Condensed Matter Physics
  • Materials Science

Background:

  • Utilizes single deoxyribonucleic acid (DNA) molecules or single-walled carbon nanotubes (SWCNTs) as templates for fabricating nanodevices.
  • Investigates superconducting devices fabricated using these molecular templates at cryogenic temperatures.
  • Focuses on the unique properties of ultra-thin nanowires, comparable in diameter to the templating molecule.

Discussion:

  • Analyzes the susceptibility of extremely thin nanowires to thermal fluctuations, specifically collective phase slips.
  • Explains how phase slips disrupt the quantum coherence of the superconducting condensate, leading to slight resistance below the critical temperature.
  • Highlights the transition from thermal fluctuation dominance to quantum fluctuation effects at low temperatures.

Key Insights:

  • Demonstrates the phenomenon of macroscopic quantum tunneling in superconducting nanowires at low temperatures.
  • Establishes molecular templating as a viable method for creating nanoscale superconducting devices.
  • Confirms the significant impact of quantum fluctuations on the electronic state of nanoscale conductors.

Outlook:

  • Suggests the broad applicability of molecular templating for synthesizing nanowires from diverse materials including normal metals, ferromagnetic alloys, and semiconductors.
  • Opens avenues for novel nanoscale electronic and quantum device development.
  • Paves the way for future research into quantum phenomena in low-dimensional superconducting systems.