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Updated: Jun 13, 2026

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach
Published on: June 10, 2021
Carbazolyl-contained phenol-pyridyl boron complexes: syntheses, structures, photoluminescent and electroluminescent
Zuolun Zhang1, Dandan Yao, Shanshan Zhao
1State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, 130012, P. R. China. hongyuzhang@jlu.edu.cn.
Abstract:
A series of phenol-pyridyl boron complexes 1-4 bearing carbazolyl-containing groups on boron centres have been designed and synthesized. The single crystals of complexes 1, 2 and 4 were grown, and the crystal structures were determined by X-ray diffraction analysis. All complexes possess very high melting points (346-385 °C) and decomposition temperatures (Td5: 397-423 °C), indicative of their high thermal stabilities. The electrochemical and photophysical properties as well as theoretical calculations were also investigated. Typical three-layer electroluminescent (EL) devices based on these organoboron complexes exhibited white electroluminescence.
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