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Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
|May 1, 2010
PubMed
Summary

Frequency upconversion was observed in praseodymium-doped tellurite glass (TNO). Energy transfer between excited praseodymium ions drives this upconversion emission, revealing insights into material bonding.

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Area of Science:

  • Materials Science
  • Solid State Physics
  • Photonics

Background:

  • Frequency upconversion in rare-earth doped glasses is crucial for applications like lasers and displays.
  • Understanding the local environment and bonding in glassy matrices influences optical properties.

Purpose of the Study:

  • To investigate frequency upconversion in praseodymium-doped tellurite-sodium oxide (TeO(2)-Na(2)O or TNO) glass.
  • To analyze the nature of bonding between praseodymium ions and the surrounding oxygen atoms.
  • To elucidate the energy transfer mechanisms responsible for upconversion.

Main Methods:

  • Excitation of triply ionized praseodymium-doped TNO glass using a tunable dye laser.
  • Calculation of covalency, bonding parameter, and the nephelauxetic effect.
  • Analysis of emission spectra to identify upconversion pathways.

Main Results:

  • Successful observation of frequency upconversion in the praseodymium-doped TNO glass.
  • Calculated bonding parameters indicate the nature of the lanthanide-oxygen interaction.
  • Energy transfer between two excited praseodymium ions was identified as the primary mechanism for upconversion.

Conclusions:

  • The TNO glass system exhibits efficient frequency upconversion in the presence of praseodymium ions.
  • The calculated bonding parameters provide valuable information on the local structure and ion-ligand interactions.
  • The dominant energy transfer process highlights the importance of ion-ion interactions in achieving upconversion.