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Updated: Jun 13, 2026

Facet-to-facet Linking of Shape-anisotropic Colloidal Cadmium Chalcogenide Nanostructures
Published on: August 10, 2017
Poly[bis(mu-4-benzoyl-1-isonicotinoylthiosemicarbazide-kappa2N:S)dichloridocadmium(II)]
Yu-Bo Wang1, Tong-Hen Pan, Qian Liang
1State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, People's Republic of China.
Abstract:
The asymmetric unit of the title complex, [CdCl(2)(C(14)H(12)N(4)O(2)S)(2)](n), consists of one Cd(II) ion located on the crystallographic inversion centre, one 4-benzoyl-1-isonicotinoylthiosemicarbazide ligand and one chloride ligand. The central Cd(II) ion adopts a distorted octahedral coordination geometry formed by two pyridyl N atoms of two ligands, two S atoms of two other ligands and two chloride ligands. The thiosemicarbazide ligands act as bridges, linking the metal ions into a two-dimensional layered structure parallel to the bc plane. Intermolecular N-H...O hydrogen bonds and C-H...pi interactions exist between adjacent layers.
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