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Related Concept Videos

¹H NMR: Interpreting Distorted and Overlapping Signals01:02

¹H NMR: Interpreting Distorted and Overlapping Signals

Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are slanted or...

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Characterizing Far-infrared Laser Emissions and the Measurement of Their Frequencies
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Multiwavenumber linearized diode laser spectra by overlapping frequency scans.

C B Dane, R Brüggemann, R F Curl

    Applied Optics
    |May 11, 2010
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    Summary
    This summary is machine-generated.

    This study introduces a new method for diode laser spectroscopy scans. It creates long, linear, and accurately calibrated scans by piecing together shorter, computer-controlled segments.

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    Area of Science:

    • Spectroscopy
    • Laser Technology
    • Analytical Chemistry

    Background:

    • Diode laser spectroscopy is a powerful analytical technique.
    • Generating long, linear, and accurately calibrated scans can be challenging.

    Purpose of the Study:

    • To describe a novel method for producing extended diode laser spectroscopy scans.
    • To ensure scans are linear in frequency and easily calibrated using reference spectra.

    Main Methods:

    • Computer-controlled current scanning of diode lasers over short segments.
    • Linearization and assembly of overlapping spectral segments.
    • Calibration using established reference spectra.

    Main Results:

    • Successfully produced long, linear diode laser spectroscopy scans.
    • Achieved accurate calibration of the generated scans.
    • Demonstrated a practical method for extending spectral acquisition range.

    Conclusions:

    • The described method provides a reliable way to obtain long, linear, and accurately calibrated diode laser spectroscopy scans.
    • This technique enhances the utility of diode laser spectroscopy for various applications.