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Related Concept Videos

Mass Analyzers: Common Types01:19

Mass Analyzers: Common Types

The quadrupole mass analyzer consists of four cylindrical metal rods arranged in a diamond carrying a DC voltage and a radio-frequency AC voltage. The motion of ions through the quadrupole depends on the field strength, causing only ions of a certain m/z to resonate successfully and strike the detector at a given field strength. Though the transmission rate for these analyzers is high, the exact elemental composition of the sample is not determined because of low resolution; however, they are...
Atomic Absorption Spectroscopy: Instrumentation01:22

Atomic Absorption Spectroscopy: Instrumentation

An atomic absorption spectrophotometer (AAS) comprises several components: a radiation source, an atomizer, a monochromator, and a detector. The radiation source can be a hollow-cathode lamp (HCL) or an electrodeless-discharge lamp (EDL), both of which provide a narrow emission line of the required wavelength. However, some instruments use continuum sources and high-resolution monochromators to achieve a narrow range of radiation.
The atomizer used in AAS can be either a flame atomizer or an...
Mass Analyzers: Overview01:13

Mass Analyzers: Overview

The mass analyzer is a crucial component of the mass spectrometer. In the ionization chamber, the vaporized sample is bombarded with a high-energy electron beam to generate a radical cation and further fragment into neutral molecules, radicals, and cations. A series of negatively charged accelerator plates accelerate the cations into the mass analyzer. The mass analyzer separates ions according to their mass-to-charge (m/z) ratios and then directs them to the detector. The common types of mass...
Mass Spectrometers01:16

Mass Spectrometers

This lesson details the instrumentation of a mass spectrometer—a physical instrument to perform mass spectrometry on analyte molecules and record the characteristic mass spectra. This is achieved via three chief functions:
Molecular Spectroscopy: Absorption and Emission01:14

Molecular Spectroscopy: Absorption and Emission

Molecules possess discrete energy levels called quantum states. Unlike atoms, which have simpler energy levels, molecules possess additional rotational and vibrational energy levels. Each energy level is separated by an energy gap, with the gaps between adjacent electronic, vibrational, and rotational levels varying significantly. The three types of energy levels in a diatomic molecule are shown in Figure 1.
MALDI-TOF Mass Spectrometry01:19

MALDI-TOF Mass Spectrometry

Mass spectrometry is a powerful characterization technique that can identify and separate a wide variety of compounds ranging from chemical to biological entities, based on their mass-to-charge ratio (m/z). The instruments that allow this detection, known as mass spectrometers, have three components: an ion source, a mass analyzer, and a detector. These spectrometers differ based on the nature of their ion source and analyzers.Matrix-assisted laser desorption ionization (MALDI) is a commonly...

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Molecular Beam Mass Spectrometry With Tunable Vacuum Ultraviolet (VUV) Synchrotron Radiation
09:53

Molecular Beam Mass Spectrometry With Tunable Vacuum Ultraviolet (VUV) Synchrotron Radiation

Published on: October 30, 2012

Multipass cell for molecular beam absorption spectroscopy.

D Kaur, A M de Souza, J Wanna

    Applied Optics
    |June 18, 2010
    PubMed
    Summary
    This summary is machine-generated.

    A novel two-spherical mirror multipass cell enables efficient laser coupling for molecular spectroscopy. This setup achieved sub-Doppler linewidths for jet-cooled hydrocarbons, advancing high-resolution molecular beam studies.

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    Area of Science:

    • Molecular Spectroscopy
    • Laser Physics
    • Physical Chemistry

    Background:

    • High-resolution molecular spectroscopy requires efficient interaction between laser light and molecular samples.
    • Multipass cells enhance interaction path length but often face challenges in coupling laser beams to molecular beams.

    Purpose of the Study:

    • To develop and characterize a novel two-spherical mirror multipass cell for improved laser coupling.
    • To apply the cell for high-resolution direct absorption spectroscopy of small hydrocarbons.

    Main Methods:

    • Design and implementation of a two-spherical mirror multipass cell with near-concentric alignment.
    • Coupling a laser beam into and out of the cell at the edges of opposite mirrors.
    • Direct absorption spectroscopy of jet-cooled acetylene, propyne, and 1-butyne in the 3-micrometer region.

    Main Results:

    • Observed an approximately parabolic reflection pattern, indicating efficient beam management within the cell.
    • Achieved forty to fifty passes of the laser beam through the molecular beam.
    • Recorded sub-Doppler linewidths as narrow as 12 MHz for the studied hydrocarbons.

    Conclusions:

    • The developed two-spherical mirror multipass cell effectively couples laser beams to collimated molecular beams.
    • The cell facilitates high-resolution, sub-Doppler direct absorption spectroscopy of jet-cooled molecules.
    • This technique offers a significant advancement for precise molecular structure and dynamics studies.