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Total synthesis of (+)-dibromophakellin and (+)-dibromophakellstatin
Takuya Imaoka1, Takafumi Akimoto, Osamu Iwamoto
1Department of Biotechnology and Life Science, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan.
Chemistry, an Asian Journal
|June 22, 2010
Abstract:
A new method for the preparation of quaternary chiral aminals has been developed that employs an enamide-type Overman rearrangement process. This methodology was applied to enantioselective total syntheses of (+)-dibromophakellin and (+)-dibromophakellstatin.

