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Updated: Jun 11, 2026
09:37
Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
The quest for silylhydroboranes: (Me(3)Si)(3)SiBH(2)
Henning Arp1, Christoph Marschner, Judith Baumgartner
1Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, 8010 Graz, Austria.
Dalton Transactions (Cambridge, England : 2003)
|July 2, 2010
Summary
Researchers synthesized a novel silylborane through reactions involving tris(trimethylsilyl)silylpotassium and borane complexes. This new compound was further derivatized, showcasing its versatile chemical reactivity.
Area of Science:
- Organometallic Chemistry
- Boron Chemistry
- Silicon Chemistry
Background:
- Boranes and silyl compounds are crucial in synthetic chemistry.
- Understanding their reactivity is key to developing new materials and catalysts.
Purpose of the Study:
- To synthesize and characterize a novel silylborane.
- To explore the reactivity of silylboranates with Lewis acids and transition metal complexes.
Main Methods:
- Reaction of BH(3)·NEt(3) with tris(trimethylsilyl)silylpotassium.
- Hydride abstraction using B(C(6)F(5))(3).
- Derivatization of the silylborane as an Et(3)N adduct.
- Treatment of the boranate with Cp(2)Ti(btmsa).
Main Results:
- Formation of a silylboranate intermediate.
- Generation of a neutral silylborane via hydride abstraction.
- Successful derivatization of the silylborane.
- Observation of ligand exchange with a titanium complex.
Conclusions:
- The study successfully synthesized and characterized a new silylborane.
- The reactivity of silylboranates with strong Lewis acids and transition metal complexes was demonstrated.
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