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Total synthesis of batatoside L
Lin Xie1, San-Yong Zhu, Xiao-Qiu Shen
1Key Laboratory of Drug Targeting and Delivery Systems, Ministry of Education, and Department of Chemistry of Medicinal Natural Products, School of Pharmacy, Sichuan University, Chengdu 610041, People's Republic of China.
Abstract:
The total synthesis of batatoside L (1), a resin glycoside possessing cytotoxicity against laryngeal carcinoma cells, has been completed in a highly convergent manner. The most crucial step in this total synthesis was the efficient construction of the 18-membered macrolactone framework through the Corey-Nicolaou macrolactonization approach.