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Updated: Jun 10, 2026

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
Published on: November 27, 2015
Generalized kinetic master plots for the thermal degradation of polymers following a random scission mechanism
Pedro E Sánchez-Jiménez1, Luis A Pérez-Maqueda, Antonio Perejón
1Instituto de Ciencia de Materiales de Sevilla, CSIC-Universidad de Sevilla, C. Americo Vespucio No. 49, 41092 Sevilla, Spain. pedro.enrique@icmse.csic.es
Abstract:
In this paper, the f(alpha) conversion functions for random scission mechanisms have been proposed to allow for the construction of generalized master plots suitable for these kinds of mechanisms. The master plots have been validated by their application to simulated data and to the thermal degradation of poly(butylene terephthalate), polyethylene, and poly(tetrafluoroethylene).
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