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Self-assembly of a nanosized, saddle-shaped, solution-stable polyoxometalate anion built from pentagonal building

Jun Yan1, Jing Gao, De-Liang Long

  • 1WestCHEM, Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, UK.

Journal of the American Chemical Society
|August 6, 2010
PubMed

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...