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Updated: Jun 9, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Control over interpenetration in lanthanide-organic frameworks: synthetic strategy and gas-adsorption properties
Haiyan He1, Daqiang Yuan, Huiqing Ma
1Key Lab for Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, People's Republic of China.
Abstract:
Two isostructural lanthanide-organic frameworks (1 and 2) with 2-fold interpenetrating nets have been synthesized based on 1,4-benzenedicarboxylic acid (H(2)BDC). By application of an organic ligand with hindrance groups and a terminal chelating ligand to replace BDC and coordinated solvates, interpenetration has been effectively controlled. The gas-sorption properties of the noninterpenetrating net have been studied.
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