Related Experiment Video
Updated: Jun 9, 2026

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
Electron-mediated CO oxidation on the TiO2(110) surface during electronic excitation
1Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, USA.
Abstract:
The role of electrons and holes in the electronically excited oxidation of adsorbed CO on TiO(2)(110) has been investigated by tuning the surface electron and hole availability by the adsorption of Cl(2) or O(2). The presence of an electron acceptor (Cl(2) or O(2)) on the TiO(2)(110) surface causes upward band bending, increasing the excited hole availability and decreasing the excited electron availability in the near surface region. This enhances O(2) desorption and depresses CO(2) production during electronic excitation. This result gives clear evidence for the first time that the electronically excited CO oxidation reaction is caused by an electron-mediated process in contrast to O(2) desorption which is mediated by holes.
More Related Videos
Related Concept Videos
Thermal and Photochemical Electrocyclic Reactions: Overview
Photochemical Electrocyclic Reactions: Stereochemistry
Selection Rules: Photochemical Activation
Heterogeneous Catalysis
Electron Transport Chain: Complex III and IV
Cycloaddition Reactions: MO Requirements for Photochemical Activation
Electron Transport Chain: Complex I and II
ROS generation is regulated and maintained at moderate levels necessary...

