Synthesis, reactivity, and electronic properties of 6,6-dicyanofulvenes
Trisha L Andrew1, Jason R Cox, Timothy M Swager
1Massachusetts Institute of Technology, Department of Chemistry, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.
Abstract:
A series of 6,6-dicyanofulvene derivatives are synthesized starting from masked, dimeric, or monomeric cyclopentadienones. The reactivities of 6,6-dicyanofulvenes relative to their parent cyclopentadienones are discussed. 6,6-Dicyanofulvenes are capable of undergoing two consecutive, reversible, one-electron reductions and are presented as potential n-type small molecules.
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