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The (4+3)-cycloaddition reaction: simple allylic cations as dienophiles

Michael Harmata1

  • 1Department of Chemistry, University of Missouri-Columbia, Columbia, Missouri 65211, USA. harmatam@missouri.edu

Chemical Communications (Cambridge, England)
|November 9, 2010
PubMed
Summary

The (4+3)-cycloaddition reaction efficiently creates seven-membered rings using allylic cations and dienes. Recent advancements enhance this synthesis through novel cation generation, stereoselective control, and applications in natural product synthesis.

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