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Related Concept Videos

IR Spectrometers01:25

IR Spectrometers

There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview01:13

Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview

Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely employed in chemistry, materials science, forensic science, and other fields where sample characterization is required. ATR has several advantages over traditional transmission IR spectroscopy, including the requirement of little to no sample preparation and the ability to analyze a wide range of samples.
The ATR process begins by directing a beam...
Infrared (IR) Spectroscopy: Overview01:09

Infrared (IR) Spectroscopy: Overview

When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation corresponding to the energy difference between the two states. The absorption of infrared (IR) radiation causes transitions between vibrational energy levels in a molecule. Therefore, IR spectroscopy is a useful analytical tool for determining the molecular structure of molecules.
Different compounds display unique properties due to their...
Total Internal Reflection Fluorescence Microscopy01:05

Total Internal Reflection Fluorescence Microscopy

Total internal reflection fluorescence microscopy or TIRF is an advanced microscopic technique used to visualize fluorophores in samples close to a solid surface with a higher refractive index, such as a glass coverslip. TIRF only allows fluorophores in proximity to the solid surface to be excited. When light from a medium with a lower refractive index (such as air) hits the glass coverslip at a critical angle, the light undergoes total internal reflection stead of passing through the glass.
IR Frequency Region: Fingerprint Region01:03

IR Frequency Region: Fingerprint Region

IR spectra are divided into two main regions: the diagnostic region and the fingerprint region. The diagnostic region of the spectrum lies above 1500 cm−1. The absorptions resulting from single-bond vibrations of the N–H, C–H, and O–H stretch at higher wavenumbers and appear on the left side of the spectrum. The stretching absorptions of the C≡C and C≡N occur between 2100–2300 cm−1. In contrast, those arising from stretching absorptions of the C=O, C=N, and C=C occur between 1600–1850 cm−1.
The...
IR Absorption Frequency: Hybridization01:21

IR Absorption Frequency: Hybridization

Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on the hybridization of the involved carbon atom and can be explained in terms of the s character of each hybridized atomic orbital.
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that stretch at a...

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Rejection of Fluorescence Background in Resonance and Spontaneous Raman Microspectroscopy
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Published on: May 18, 2011

Antireflection coatings designed for two different infrared substrates.

J A Dobrowolski, P Panchhi, M High

    Applied Optics
    |November 12, 2010
    PubMed
    Summary

    This study demonstrates novel antireflection coatings that reduce reflectance for two substrates simultaneously. This innovation offers significant time and cost savings for small-scale thin-film production.

    Area of Science:

    • Materials Science
    • Optical Engineering
    • Thin-Film Technology

    Background:

    • Conventional antireflection coatings are optimized for single substrates.
    • Simultaneous reduction of reflectance for multiple substrates presents design challenges.
    • Small thin-film production facilities seek cost-effective solutions.

    Purpose of the Study:

    • To design and evaluate normal-incidence antireflection coatings capable of reducing reflectance for two distinct substrates concurrently.
    • To assess the trade-offs between performance and cost-effectiveness in such multi-substrate coatings.
    • To provide numerical examples and experimental validation for the proposed coating designs.

    Main Methods:

    • Design of multi-substrate antireflection coatings using optical modeling.

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  • Numerical simulations for specific substrate pairs (ZnS/ZnSe, Si/Ge, ZnS/Ge).
  • Experimental fabrication and measurement of a representative coating design.
  • Main Results:

    • Successful design of antireflection coatings for simultaneous dual-substrate reflectance reduction.
    • Demonstrated performance trade-offs compared to conventional single-substrate coatings.
    • Numerical examples and experimental data show good agreement, validating the design approach.

    Conclusions:

    • It is feasible to engineer antireflection coatings for dual-substrate applications.
    • These coatings offer substantial time and cost benefits for small-scale manufacturing despite minor performance compromises.
    • The validated design methodology is applicable to various substrate combinations.