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Split Point Analysis and Uncertainty Quantification of Thermal-Optical Organic/Elemental Carbon Measurements
Published on: September 7, 2019
Ten methods for calculating the uncertainty of measurement
1Ventura County Sheriff's Forensic Services Bureau, 800 S. Victoria Ave, Ventura, CA 93009, USA. jack.wallace@ventura.org
Abstract:
While forensic laboratories are coming under increasing pressure to provide meaningful estimates of measurement uncertainty, there has been little discussion of this topic in the literature. This article summarizes ten bases for estimating this parameter: (1) proficiency tests; (2) readability limits; (3) independent reference materials; (4) operational limits applied during calibration; (5) expert judgment; (6) precision control samples without (6) and with (7) contributions from extramural sources of error; (8) error budgets; (9) historical performance; and (10) ruggedness tests. Based on the assumptions underlying each approach, the forensic community will need to apply a variety of discipline-specific approaches to arrive at satisfactory estimates of measurement uncertainty.
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