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Chiral poly(fluorene-alt-benzothiadiazole) (PFBT) and nanocomposites with gold nanoparticles: plasmonically and

Heong Sub Oh1, Sha Liu, HongSub Jee

  • 1Institute for Lasers, Photonics and Biophotonics, Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260, USA.

Journal of the American Chemical Society
|November 25, 2010
PubMed

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Chirality at Nitrogen, Phosphorus, and Sulfur02:30

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...