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Updated: Jun 6, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Bis[S-benzyl-3-(4-n-octyloxybenzylidene)dithiocarbazato-κ(2)N(3),S']palladium(II)
M T H Tarafder1, M A A A A Islam, M B H Howlader
1Department of Chemistry, Rajshahi University, Rajshahi 6205, Bangladesh.
Abstract:
In the title compound, [Pd(C(23)H(29)N(2)OS(2))(2)], the Pd(II) atom displays the expected square-planar coordination geometry. However, the trans configuration, which allows the Pd(II) atom to be located on a crystallographic inversion centre, is unusual with respect to the cis arrangement found in analogous Pd complexes comprising similar N,S-chelating ligands.
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