Related Experiment Video
Updated: Jun 6, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
[M(dap)3]InSb3S7 (M = Co, Ni): two novel open-framework thioindate-thioantimonates with 8-, 12-, and 16-ring
Jian Zhou1, Litao An, Feng Zhang
1Department of Chemistry and Biology, Yulin Normal University, Yulin 537000, China.
Abstract:
Two novel open-framework thioindate-thioantimonates [M(dap)3]InSb3S7 [M = Co(1), Ni (2); dap = 1,2-diaminopropane] have been solvothermally synthesized and structurally characterized. 1 and 2 consist of InS4 tetrahedra and SbS3(3-) trigonal pyramids, which are interconnected to form the first examples of three-dimensional In-Sb-S open frameworks with 8-, 12-, and 16-ring intersecting channels.
More Related Videos
07:14Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
06:35Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Related Concept Videos
Valence Bond Theory
Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can be...
Coordination Number and Geometry
Hybridization of Atomic Orbitals II
Structure and Nomenclature of Thiols and Sulfides
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...