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Updated: Jun 5, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Bis[2-(2-hydroxy-3-meth-oxy-phen-yl)benzimidazolium] tetrachlorido-cuprate(II) methanol disolvate
Ruiting Xue1, Meiju Niu, Jianmin Dou
1College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
Abstract:
In the title compound, (C(14)H(13)N(2)O(2))(2)[CuCl(4)]·2CH(4)O, the geometry of the CuC1(4) (2-) ions (Cu site symmetry 2) is inter-mediate between tetra-hedral and square-planar. The dihedral angle between the benzimidazole and benzene ring systems is 8.74(14)°. A network of N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds helps to consoldiate the structure. Aromatic π-π stacking inter-actions involving the benzimidazole ring system, with a centroid-centroid distance of 3.785 (3) Å, also occur.
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