Related Experiment Video
Updated: Jun 5, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
(η-Benzene)(2,2'-bipyridine-κN,N')chloridoruthenium(II) chloride methanol sesquisolvate
1Chemistry Department, University of Canterbury, PO Box 4800, Christchurch, New Zealand.
Abstract:
In the title compound, [RuCl(C(6)H(6))(C(10)H(8)N(2))]Cl·1.5CH(4)O, the Ru(II) atom is in a distorted octa-hedral environment coordinated by an η(6)-benzene ring, a chelating 2,2'-bipyridine ligand and a chloride ion. The asymmetric unit is completed by a chloride anion and two methanol mol-ecules, one of which is disordered about a centre of inversion with an occupancy of 0.5. It is an example of a ruthenium complex with a less sterically congested environment than in similar derivatives. In the crystal structure, O-H⋯Cl hydrogen bonds, together with π-π stacking inter-actions [centroid-centroid distances of 3.472Å(2) Å], stabilize the structure.
More Related Videos
10:51The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
05:34Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
Published on: December 16, 2019
Related Concept Videos
Structure of Benzene: Kekulé Model
He proposed that benzene has a cyclic structure of six carbon atoms attached to one hydrogen atom each, with three alternating pi bonds.
Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism
Electrophilic Aromatic Substitution: Chlorination and Bromination of Benzene
Nomenclature of Aromatic Compounds with Multiple Substituents
For disubstituted benzene derivatives, with two groups attached to the benzene ring, three constitutional isomers are possible. For example, consider dimethyl benzene, often called xylene, where the second methyl group can be substituted at the second, third, or fourth carbon. The relative position of the substituents is represented by prefixes ortho, meta, or...
Structure of Benzene: Molecular Orbital Model
Electrophilic Aromatic Substitution: Nitration of Benzene