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Updated: Jun 5, 2026
11:51
Facile Preparation of 4-Substituted Quinazoline Derivatives
Published on: February 15, 2016
2,2,3,3'-Tetra-phenyl-7,7'-biquinoxaline.
Acta Crystallographica. Section E, Structure Reports Online
|January 5, 2011
Summary
The crystal structure of C(40)H(26)N(4) reveals molecules forming one-dimensional chains through C-H⋯N and C-H⋯π(arene) interactions. These interactions link molecules around inversion centers, dictating the compound
Area of Science:
- Crystallography
- Supramolecular Chemistry
- Organic Chemistry
Background:
- Understanding intermolecular interactions is crucial for predicting crystal packing and material properties.
- Crystal structure analysis provides detailed insights into molecular arrangement and bonding.
Purpose of the Study:
- To determine and analyze the crystal structure of the title compound, C(40)H(26)N(4).
- To investigate the intermolecular interactions governing the crystal packing.
Main Methods:
- Single-crystal X-ray diffraction was employed to obtain the crystal structure.
- Analysis of non-covalent interactions, including hydrogen bonds (C-H⋯N) and C-H⋯π(arene) interactions, was performed.
Main Results:
- The title compound, C(40)H(26)N(4), crystallizes with molecules located on crystallographic inversion centers.
- Molecules are linked into one-dimensional chains via C-H⋯N interactions around these inversion centers.
- Extended C-H⋯π(arene) interactions further stabilize the crystal lattice.
Conclusions:
- The crystal structure is characterized by a network of C-H⋯N and C-H⋯π(arene) interactions.
- These interactions dictate the formation of 1D chains and overall crystal packing.
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