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Updated: Jun 5, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
4-(9-Anthryl)-2-methylbutyn-2-ol
Irena Bylińska1, Artur Sikorski, Wiesław Wiczk
1Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.
Abstract:
There are two mol-ecules in the asymmetric unit of the title compound, C(19)H(16)O. Neighbouring mol-ecules are linked through O-H⋯O hydrogen bonds into an R(4) (4)(8) ring motif. There are also C-H⋯π hydrogen and π-π inter-actions. The mol-ecules are either parallel to each other or are inclined at an angle of 12.5 (1)°.
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