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![The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
trans-Tetra-iodidobis(tri-p-tolyl-phosphine oxide-κO)tin(IV)
Marina Hitosugi-Levesque1, Joseph M Tanski
1Department of Chemistry, Vassar College, Poughkeepsie, NY 12604, USA.
Abstract:
The centrosymmetric title compound, [SnI(4)(C(21)H(21)OP)(2)], is a monomeric complex that displays a nearly octa-hedral coordination of tin(IV), with an Sn-O bond distance of 2.159 (2) Å and an average Sn-I bond distance of 2.79 (3) Å.
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