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Updated: Jun 5, 2026

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
1-Ethyl-1H-2,1-benzothia-zin-4(3H)-one 2,2-dioxide
Abstract:
In the title compound, C(10)H(11)NO(3)S, there is distorted tetra-hedral geometry around the S atom. The heterocyclic thia-zine ring adopts a half-chair conformation. The ethyl and sulfonyl groups form dihedral angles of 82.53 (13) and 88.91 (9)°, respectively, with the plane formed by the benzothia-zine ring, excluding the S atom; the S atom and the ethyl group lie on opposite sides of the ring. The mol-ecules are linked into dimers by inter-molecular C-H⋯O hydrogen bonds involving benzene C-H and carbonyl O atoms, thus forming eight-membered rings. The dimers are linked into chains via inter-actions of a similar type. There is an intra-molecular C-H⋯O hydrogen bond.
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