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Updated: Jun 5, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
(4-Chloro-benzoato)bis(5-methyl-2-pyridylamine)silver(I)
Yong-Qiang Tian1, Tong Shen, Wu-Xia Liu
1School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.
Abstract:
The title compound, [Ag(C(7)H(4)ClO(2))(C(6)H(8)N(2))(2)], is a mononuclear silver(I) complex. The Ag(I) atom is three-coordinated by two pyridine N atoms from two 5-methyl-pyridin-2-ylamine ligands and by one O atom of a 4-chloro-benzoate ligand, forming a distorted T-shaped coordination. In the crystal structure, the mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis.
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