trans-4-(Phenoxy-meth-yl)cyclo-hexane-carboxylic acid.
Acta Crystallographica. Section E, Structure Reports Online
|January 5, 2011
Summary
This study details the crystal structure of a key phenolic ether synthesis model compound. It reveals insights into molecular conformation and intermolecular hydrogen bonding in the solid state.
Area of Science:
- Organic Chemistry
- Crystallography
- Chemical Synthesis
Background:
- Phenolic ethers are crucial in organic synthesis.
- Model compounds aid in understanding complex reaction pathways.
- Crystal structure analysis provides detailed molecular information.
Purpose of the Study:
- To elucidate the crystal structure of a specific C(14)H(18)O(3) compound.
- To investigate the conformational preferences of the cyclo-hexane ring.
- To identify intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed.
- The crystal structure was analyzed to determine atomic coordinates and bonding.
- Conformational analysis of the cyclo-hexane ring was performed.
Main Results:
- The cyclo-hexane ring adopts a chair conformation.
- Adjacent molecules are linked via O-H⋯O hydrogen bonds.
- The study provides precise structural data for the title compound.
Conclusions:
- The determined crystal structure offers valuable insights for phenolic ether synthesis.
- Understanding hydrogen bonding patterns is key for predicting solid-state behavior.
- This research contributes to the fundamental knowledge of organic crystal structures.
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