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Updated: Jun 5, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
4-Eth-oxy-N-(3-phenyl-prop-2-enyl-idene)aniline
Abstract:
The title compound, C(17)H(17)NO, was prepared by the condensation of cinnamaldehyde with p-phenetidine in ethanol. The prop-2-enyl-idene group exhibits an E configuration at the N=C and C=C double bonds, with C-N-C-C and C-C-C-C torsion angles of -179.9 (3) and -175.9 (3)°, respectively. The prop-2-enyl-idene group is not strictly planar [maximum deviation = 0.054 (4) Å] and forms dihedral angles of 28.0 (3) and 34.9 (3)° with the attached aromatic rings.
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