Related Experiment Video
Updated: Jun 5, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
2,2'-Bis(9-hydr-oxy-9-fluoren-yl)biphen-yl-ethyl acetate (1/1)
Abstract:
In the title host-guest compound, C(38)H(26)O(2)·C(4)H(8)O(2), the ethyl acetate mol-ecule (guest), which adopts a fully extended conformation, and the biphenyl derivative (host) are connected via O-H⋯O hydrogen bonds [H⋯O = 1.90 (3) Å] into discrete assemblies. The hydro-carbon skeleton of the host mol-ecule deviates only slightly from C(2) symmetry. The OH groups of the host are involved in intra-molecular O-H⋯O hydrogen bonding [H⋯O = 1.83 (3) Å].
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