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Updated: Jun 5, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Synthesis, structural characterization, and reactivity of Group 4 metallacarboranes bearing the ligand
Dongmei Liu1, Hao Shen, Yaorong Wang
1Department of Chemistry and Center of Novel Functional Molecules, The Chinese University of Hong Kong, Shatin, NT, Hong Kong, China.
Abstract:
A new organic-inorganic hybrid ligand H(2)C(C(5)Me(4)H)(C(2)B(10)H(11)) (2) has been prepared. A selective deboration reaction with piperidine in ethanol resulted in the isolation of [Me(3)NH][H(2)C(C(5)Me(4)H)(C(2)B(9)H(11))] (3). An amine-elimination reaction of 3 with [Zr(NMe(2))(4)] produced a neutral metal-amide complex [η(5):η(5)-H(2)C(C(5)Me(4))(C(2)B(9)H(10))]Zr(NMe(2))(NHMe(2)) (4). The double-ring-opening reaction of 4 with tetrahydrofuran (THF) afforded [η(5):η(5)-H(2)C(C(5)Me(4))(C(2)B(9)H(10))]Zr (OCH(2)CH(2)CH(2)CH(2))(2)N(CH(3))(2) (5). Treatment of the trianionic salt of 3 with [MCl(4)(thf)(2)] gave complexes [{η(5):η(5)-H(2)C(C(5)Me(4))(C(2)B(9)H(10))}M(μ-Cl)(2)][Li(thf)(2)] (M=Zr (6), Hf (7)). Reaction of 6 with LiCH(2)TMS generated the ionic species [{η(5):η(5)-H(2)C(C(5)Me(4))(C(2)B(9)H(10))}Zr(CH(2)TMS)(2)][Li(thf)(3)] (9). Interaction of complex 6 with KCH(2)(NMe(2))-o-C(6)H(4) led to the formation of the neutral metal alkyl complex [η(5):η(5)-H(2)C(C(5)Me(4))(C(2)B(9)H(10))]Zr[σ:σ-CH(2)(NMe(2))-o-C(6)H(4)] (10). All complexes have been fully characterized by various spectroscopic techniques and elemental analyses. Some were further confirmed by single-crystal X-ray analyses.
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