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Preparation of Liquid-exfoliated Transition Metal Dichalcogenide Nanosheets with Controlled Size and Thickness: A State of the Art Protocol
Published on: December 20, 2016
Visibility of dichalcogenide nanolayers
M M Benameur1, B Radisavljevic, J S Héron
1Electrical Engineering Institute, School of Engineering, EPFL, Lausanne, Switzerland.
Researchers optimized optical imaging to detect ultrathin dichalcogenide nanocrystals, specifically molybdenum disulfide (MoS2) and tungsten diselenide (WSe2) layers. This method allows distinguishing between single, double, and triple layers using optical contrast.
Area of Science:
- Materials Science
- Nanotechnology
- Optics
Background:
- Dichalcogenides (MX2) are layered materials with tunable electrical properties.
- Ultrathin two-dimensional (2D) materials offer unique electronic and optical characteristics.
- Optical detection methods are crucial for characterizing nanoscale materials.
Purpose of the Study:
- To establish optimal imaging conditions for the optical detection of ultrathin dichalcogenide nanocrystals.
- To develop an optical model for predicting contrast of nanolayers on SiO2 substrates.
- To differentiate between single, double, and triple layers of MoS2, WSe2, and NbSe2.
Main Methods:
- Development of a simple optical model to calculate contrast for nanolayers on SiO2 wafers.
- Extension of the optical model for imaging using the green channel of a video camera.
- Utilizing Atomic Force Microscopy (AFM) and optical imaging for confirmation.
Main Results:
- Confirmed optical detection of single layers of MoS2 and WSe2 on 90 nm and 270 nm SiO2.
- Demonstrated the ability to distinguish between single, double, and triple layers of MoS2 and WSe2 via contrast measurements.
- Observed and discussed discrepancies in the optical detection of NbSe2.
Conclusions:
- Optimal optical imaging conditions were identified for detecting and characterizing ultrathin dichalcogenide layers.
- The developed optical model provides a reliable method for predicting contrast and layer number.
- Further investigation is needed to understand the behavior of NbSe2 using this optical technique.
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