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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
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Pd(II) and Pt(II) complexes of 2-(2'-pyridyl)-4,6-diphenylphosphinine: synthesis, structure, and reactivity

Ariadna Campos-Carrasco1, Leen E E Broeckx, Jarno J M Weemers

  • 1Department of Chemical Engineering and Chemistry, Schuit Institute of Catalysis, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|February 15, 2011
PubMed

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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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