Related Experiment Video
Updated: Jun 4, 2026

Experimental Methods for Trapping Ions Using Microfabricated Surface Ion Traps
Published on: August 17, 2017
Counter-ions at charged walls: two-dimensional systems
1Laboratoire de Physique Théorique et Modèles Statistiques, Université Paris-Sud, UMR CNRS 8626, 91405, Orsay, France. Ladislav.Samaj@savba.sk
Abstract:
We study equilibrium statistical mechanics of classical point counter-ions, formulated on 2D Euclidean space with logarithmic Coulomb interactions (infinite number of particles) or on the cylinder surface (finite particle numbers), in the vicinity of a single uniformly charged line (one single double layer), or between two such lines (interacting double layers). The weak-coupling Poisson-Boltzmann theory, which applies when the coupling constant [Formula: see text] is small, is briefly recapitulated (the coupling constant is defined as [Formula: see text] [Formula: see text] [Formula: see text] e (2) , where [Formula: see text] is the inverse temperature, and e the counter-ion charge). The opposite limit ( [Formula: see text] [Formula: see text] ∞ is treated by using a recent method based on an exact expansion around the ground-state Wigner crystal of counter-ions. These two limiting results are compared at intermediary values of the coupling constant [Formula: see text] = 2[Formula: see text] ([Formula: see text] = 1, 2, 3) , to exact results derived within a 1D lattice representation of 2D Coulomb systems in terms of anti-commuting field variables. The models (density profile, pressure) are solved exactly for any particles numbers N at [Formula: see text] = 2 and up to relatively large finite N at [Formula: see text] = 4 and 6. For the one-line geometry, the decay of the density profile at asymptotic distance from the line undergoes a fundamental change with respect to the mean-field behavior at [Formula: see text] = 6 . The like-charge attraction regime, possible for large [Formula: see text] but precluded at mean-field level, survives for [Formula: see text] = 4 and 6, but disappears at [Formula: see text] = 2 .
Related Concept Videos
Electrochemical Systems
Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Electric Field of Two Equal and Opposite Charges
A separation of the positive and negative charges can lead to a weak, remnant effect of the positive and negative charges. The expectation is that the more the distance between the positive and...
The Electrical Double Layer
Intermolecular Forces
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...

