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Work probability distribution and tossing a biased coin.

Arnab Saha1, Jayanta K Bhattacharjee, Sagar Chakraborty

  • 1S N Bose National Centre for Basic Sciences, Saltlake, Kolkata, India. arnab@bose.res.in

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|March 17, 2011
PubMed
Summary

Rare events in dissipated work, analogous to biased coin tosses, enable quantitative work probability distributions for Jarzynski equality. This provides a system-independent method for constructing these distributions.

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Area of Science:

  • Statistical mechanics
  • Non-equilibrium thermodynamics
  • Probability theory

Background:

  • The Jarzynski equality relates equilibrium free energy differences to non-equilibrium work measurements.
  • Dissipated work in non-equilibrium processes often exhibits rare events that are crucial for understanding system behavior.
  • Large deviation theory provides a framework for analyzing the probability of rare events.

Purpose of the Study:

  • To develop a quantitative work probability distribution for the Jarzynski equality.
  • To propose a system-independent method for constructing this distribution.
  • To explore the role of rare events in non-equilibrium statistical mechanics.

Main Methods:

  • Mapping rare events in dissipated work to large deviation phenomena.
  • Utilizing concepts from biased coin toss models.
  • Developing a theoretical framework for work probability distributions.

Main Results:

  • Demonstrated that rare events in dissipated work are sufficient to yield a quantitative work probability distribution for the Jarzynski equality.
  • Proposed a general recipe for constructing work probability distributions.
  • Established a connection between Jarzynski equality and large deviation theory.

Conclusions:

  • The developed framework offers a novel approach to understanding and modeling rare events in physical phenomena.
  • The proposed method for constructing work probability distributions is independent of specific system details.
  • This work is expected to be valuable for various applications in statistical physics and beyond.