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Updated: Jun 3, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Hybrid polyoxometalates: Keggin and Dawson silyl derivatives as versatile platforms
B Matt1, S Renaudineau, L-M Chamoreau
1Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, Université Pierre et Marie Curie-Paris 06, 4 place Jussieu, Case 42, 75252 Paris Cedex 05, France.
Abstract:
A new series of polyoxometalate-based hybrids has been synthesized. These covalently linked organic-inorganic materials represent valuable elementary building blocks ready for postfunctionalization, using classical organic reactions and couplings. This approach is exemplified by the grafting of an organic chromophore via a Sonogashira coupling.
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